The 49-year-old hosted the show in a chic Rachel Zoe jumpsuit – and we're obsessed.
The black design featured 70s-inspired flares and a quirky asymmetric neckline.
For an added splash of glamour, there was a fine gold trim across the straps and around the waistline.
Tess kept her accessories to a minimum, opting for a pair of gold drop earrings and a ring on her little finger.
Her hair had been styled into a glamorous blow-dry, and she was rocking smoky eyes and coffee-coloured lips.
- Rachel Zoe Lucy embellished crepe jumpsuit, £565 from Net-A-Porter – buy now
The all-in-one was definitely a hit over on Twitter, with numerous Children In Need viewers asking where it was from.
One tweeted: "Absolutely love that jumpsuit that @TessDaly is wearing on @BBCCiN wonder where it's from?"
Another wrote: "I need @TessDaly jumpsuit. It's glittery! #CIN."
Unfortunately, the designer piece retails at an eye-watering £565.
There aren't many of us who can justify that kind of splurge, so we've tracked down some incredible dupes.
Boohoo's piece has a similar cinched-in waist and wide legs.
It's just £16 – so if you're missing Tess's metallic detailing, you should have enough left over to pick up a gold choker.
Love Tess's unique neckline? New Look's £15 version has an eye-catching cross-over strap.
And if you're particularly drawn to the trimming on Rachel Zoe's number, InTheStyle's bardot piece will be right up your street.
Amazingly, it's currently reduced from £19.99 to £9.99.
- Square neck wide leg jumpsuit, £16 from Boohoo – buy now
- Black frill neck trim cross strap jumpsuit, £15 from New Look – buy now
- Thalia black Greek key tape trim bardot jumpsuit, £9.99 from InTheStyle – buy now
We know what we'll be treating ourselves to this weekend.
In more fashion news, Holly Willoughby's £55 sequin Marks & Spencer dress has shoppers obsessed… but it's already selling out.
Primark is selling a dupe of Topshop's leopard-print denim skirt – and it's £20 cheaper.
And Poundland's clothing brand Pep & Co is selling Victoria's Secret-inspired lingerie, with prices starting from £2.
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